A Kinetic Study of 2-Amino-4-(Methyl-Thio) Butanoic Acid By Quinaldinium Fluorochromate In Selected Hydrophilic Solvent Medium

Life Sciences-Microbiology

Authors

  • A. Elavarasan Department of Chemistry, Periyar University, Periyar PalkalaiNagar, Salem-636 011, Tamil Nadu, India
  • J. Dharmaraja Department of Chemistry, Arignar Anna Govt. Arts College, Vadachennimalai, Attur-636 121, Tamil Nadu, India
  • V.Raj Department of Chemistry, Periyar University, Periyar PalkalaiNagar, Salem-636 011, Tamil Nadu, India
  • B.Harikrishnan Department of Bio-Chemistry,King Nandhivarman College of Arts and Science, Vandavasi, Thellar-604406, Tiruvannamalai, Tamilnadu, India
  • S.Vadivel Department of Chemistry, Periyar University, Periyar PalkalaiNagar, Salem-636 011, Tamil Nadu, India

DOI:

https://doi.org/10.22376/ijpbs/lpr.2021.11.6.L30-35

Keywords:

Chromium VI, Organic substrate, Oxidation, Product, Mechanism, solvent.

Abstract

A Major role in oxidation kinetics is to determine the reaction mechanism that comprise chemical reaction. In the present paper  we derived rate  law for reaction mechanism  and to  recognized  the  order of reaction, give rate  equation, calculate the  rate constant.   Identify  the   product  of  this  oxidation  reaction.The  chemical  oxidation  of  2-Amino-4-methyl  thio-butanoic  acid  by Quinaldinium Fluorochromate was studied  in 50-50 (v/v)  selected   hydrophilic solvent medium at 308 Kelvin. The reaction is acid catalysed  and  exhibits  first  order  dependence with  respect  to   oxidant,   substrate,  and  fractional  order  respect  to   H+  ion concentrations.  Chemical  oxidation  kinetics  is  the   study  of  the   rate   of  chemical  reaction.the  factors     Manganesh  sulphate, Acrylonitrile, Sodium perchlorate that affect these  rates (or) not, and draw of ln Kobs/T verses 1/T energy diagram to find the activation energy.  Addition  of  sodium  perchlorate  slightly  decreases  the  rate   of  reaction.  However,   Acrylonitrile  is  not  induced  by  the polymerization reaction, showing that  there  is no free radical route.  Added Mn2+ increases with slightly increase rate  in the  reaction medium. 2-Amino-4-(MethylThio)-Butanoic acid by Quinaldinium Fluorochromate has not  been reported. Hence, the investigation of oxidation  of  2-Amino-4-Methyl  Thio-Butanoic  acid  by  QNFC   in  selected  hydrophilic  solvent  medium  and  the   corresponding mechanistic  aspects   are   discussed   in  this   research  paper.   A  systematic  kinetic  work   carried  out   to   explore  the   physical characterization of the  reactance.   The  characterstic effects like  Substrate,  Oxidant,  Perchloric acid,  Solvent, Sodium perchlorate, Acrylonitrile, Manganes sulphate and Influence Temperature it clearly shows effect on that reaction path. The process  was carried out at four different temperatures to determine the activation conditions. The measured  kinetic findings ΔH#  and ΔS# are derived from the value.

 

Published

2022-07-11

How to Cite

A. Elavarasan, J. Dharmaraja, V.Raj, B.Harikrishnan, & S.Vadivel. (2022). A Kinetic Study of 2-Amino-4-(Methyl-Thio) Butanoic Acid By Quinaldinium Fluorochromate In Selected Hydrophilic Solvent Medium: Life Sciences-Microbiology. International Journal of Life Science and Pharma Research, 11(6), 30–35. https://doi.org/10.22376/ijpbs/lpr.2021.11.6.L30-35

Issue

Section

Research Articles